Sorption enhanced aqueous phase reforming of biodiesel byproduct glycerol for hydrogen production over Cu-Ni bimetallic catalysts supported on gelatinous MgO

Hydrogen production from sorption enhanced aqueous phase reforming (APR) of biodiesel byproduct glycerol was studied by Ni-based monometallic and bimetallic catalysts supported on gelatinous MgO supports. Compared with Ni-based monometallic catalyst, the H2 selectivity and glycerol conversion of the Cu–Ni bimetallic catalyst were found to be increased more than 3% and 30%, respectively. Meanwhile, higher reaction temperature was found to have higher H2 yield with lower H2 selectivity. The H2 yield using the catalyst with gelatinous MgO support was 1.25 times higher than that of calcined support. Through in-situ CO2 capture, the addition of CaO to the Cu–Ni bimetallic catalyst increased more than 58.3% and 14.4% of the H2 yield and selectivity, respectively. An analysis about liquid product component indicate that the presence of CaO promote the further cleavage of the C–C bond, which further increased the conversion of glycerol. Furthermore, it was found that the presence of CaO could also improve the stability of the catalyst through the control experiments. [Display omitted] •Sorption enhanced APR to H2 with in-situ CO2 capture was studied.•Monometallic and bimetallic supported on MgO were developed.•Cu–Ni supported on gelatinous MgO exhibited good APR performance.•H2 yield by gelatinous MgO support was 1.25 times higher than that of calcined MgO.•Presence of CaO in APR improved conversion, selectivity, and stability.