Frequency tunable Ni–Ti‐substituted Ba–M hexaferrite for efficient electromagnetic wave absorption in 8.2–75 GHz range

The development of 5G telecommunication technology has seen a high demand for effective electromagnetic (EM) wave absorbers in the millimeter wave (mmWave) band. Because hexagonal M‐type ferrite is known to have high ferromagnetic resonance (FMR) in the 5G band frequency, it has attracted significant attention as a mmWave absorber. However, study of the relationship between magnetocrystalline anisotropy, FMR frequency, and EM wave absorption performance in the mmWave band remains insufficient. In this study, Ni–Ti‐substituted M‐type barium ferrite (Ba–M ferrite) was synthesized using the citrate sol–gel method, and the change in the magnetic properties caused by Ni–Ti substitution was analyzed. The complex permittivity, permeability, and reflection loss (RL) of the Ni–Ti‐substituted Ba–M ferrite composites in the 8.2–75 GHz broadband frequency range were also studied. The EM wave absorption frequency, which is governed by the FMR frequency, could be tuned by controlling the amount of substituted Ni–Ti ions in the Ba–M ferrite. The prepared EM wave absorber exhibited excellent EM wave absorption properties with an RL of −52 dB at 29.5 GHz and a matching thickness of 0.95 mm. This study provides insights into a frequency‐tunable EM wave absorber with enhanced absorption properties, attained by changing the magnetic properties of Ni–Ti‐substituted M‐type hexaferrites in the mmWave frequency band. [Display omitted] •A single-phase Ni–Ti-substituted Ba–M ferrites were synthesized by citrate sol-gel method.•The electromagnetic properties were studied in a wide frequency range from 8.2 GHz to 75 GHz.•Electromagnetic wave absorption frequency was tuned by controlling the ferromagnetic resonance frequency.•Optimum reflection loss of −52 dB at 29.5 GHz and an EAB of 10.05 GHz were obtained at 0.95 mm thickness.