Temperature-dependent defect evolution and electrochemical performance enhancement of Na3V2(PO4)2F3

In this paper, we reported on the lattice distortion, surface morphologies, vacancy defects and electrochemical performance that had been observed in Na3V2(PO4)2F3 prepared at different annealing temperatures. X-ray diffraction indicated that all the samples were single phase materials with tetragonal structure and exhibited lattice distortion with the increase of annealing temperatures. A possible mechanism causing the strain-induced lattice distortion had been discussed. Moreover, scanning electron microscopy and positron annihilation techniques were used to study the grain size and vacancy defects as a function of annealing temperatures. The superior electrochemical performance of Na3V2(PO4)2F3 electrode was obtained at the annealing temperature of 350 °C with 167.73 F·g−1 specific capacitance and 85% capacitance retention. The better electrochemical performance was due to the synergistic effects of grain size and vacancy defect regulated by the annealing temperatures. These results could provide experimental basis for enhancing electrochemical performance of Na3V2(PO4)2F3 in sodium-ion battery area applications. •The microstructure and electrochemical properties of Na3V2(PO4)2F3 could be regulated by annealing temperatures.•The positron annihilation technology was used to characterize the evolution of microdefects in Na3V2(PO4)2F3.•The synergistic effects of grain size and defect concentration promoted the electrochemical performance of Na3V2(PO4)2F3.