Interplay of magnetic and electric coupling across the spin density wave to conical magnetic ordering in a BaHoFeO4 spin-cluster chain compound

In this study, we performed a detailed analysis of the magnetoelectric properties of a polycrystalline BaHoFeO4 system. Rietveld refinement of the synchrotron x-ray powder diffraction pattern (SXRD) with space group Pnma confirmed that the orthorhombic crystal structure was preserved down to the low...

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Veröffentlicht in:Journal of alloys and compounds 2023-05, Vol.942, p.169017, Article 169017
Hauptverfasser: Prashanth, C.H., Yen, T.W., Tiwari, Ajay, Athira, P., Huang, S.M., Poojitha, Bommareddy, Gulo, D.P., Liu, H.L., Wang, C.W., Lin, Y.K., Chuang, Y.C., Lai, Y.C., Jyothinagaram, Krishnamurthy, Yang, H.D., Kakarla, D. Chandrasekhar
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Sprache:eng
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Zusammenfassung:In this study, we performed a detailed analysis of the magnetoelectric properties of a polycrystalline BaHoFeO4 system. Rietveld refinement of the synchrotron x-ray powder diffraction pattern (SXRD) with space group Pnma confirmed that the orthorhombic crystal structure was preserved down to the lowest temperature (T) = 15 K. The DC magnetization indicated complex magnetic behavior with multiple magnetic transitions at TN1 = 49 K, TN2 = 36 K, and TN3 = 7 K. The complex interplay of 3d and 4f magnetic sublattices, and the competing interactions of two different Fe-sites can explain the field (H)-induced metamagnetic behavior in BaHoFeO4 at T 
ISSN:0925-8388
1873-4669
DOI:10.1016/j.jallcom.2023.169017