Flash vacuum pyrolysis of aryl propargyl ethers
Flash vacuum pyrolysis (FVP) of aryl propargyl ether 9 produces 2-methylbenzofuran 21, 2H-chromene indanone 22 and benzocyclobutene 23. o-chloro- and bromo-aryl propargyl ethers 10 &11 resulted mainly in methylbenzofurans 25, 26 &29 and 2H-chromene derivative 27. On the other hand, FVP of ar...
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Veröffentlicht in: | Journal of analytical and applied pyrolysis 2022-10, Vol.167, p.105638, Article 105638 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Flash vacuum pyrolysis (FVP) of aryl propargyl ether 9 produces 2-methylbenzofuran 21, 2H-chromene indanone 22 and benzocyclobutene 23. o-chloro- and bromo-aryl propargyl ethers 10 &11 resulted mainly in methylbenzofurans 25, 26 &29 and 2H-chromene derivative 27. On the other hand, FVP of arylpropargyl ethers with an active substituent at the ortho position of the aryl group 12-15 &20 has resulted in interesting, unexpected products. All products were analyzed, fully characterized, and identified. Mechanisms are proposed for most of these FVP reactions.
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•FVP reaction for twelve aryl propargyl ethers were performed.•Reaction products were analyzed, characterized, and identified.•Non-ortho substituted aryl ethers chose Claisen-rearrangement leading to 2-indanones and benzocyclobutene.•An active function group at the ortho position interacts with carbene intermediates to form interesting unexpected products. |
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ISSN: | 0165-2370 1873-250X |
DOI: | 10.1016/j.jaap.2022.105638 |