Synthesis of MnMoO4/α-MoO3 composite materials for supercapacitor

We have successfully synthesized MnMoO4/MoO3 composite materials tailored for supercapacitor applications. The supercapacitive performance of the MnMoO4/α-MoO3 composite materials was evaluated using cyclic voltammetry and constant current charge–discharge methods. The synthesis yielded an ideal com...

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Veröffentlicht in:Inorganic chemistry communications 2024-12, Vol.170, p.113481, Article 113481
Hauptverfasser: Song, Y.Z., Liu, Z.X., Huang, Y.A.
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Sprache:eng
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Zusammenfassung:We have successfully synthesized MnMoO4/MoO3 composite materials tailored for supercapacitor applications. The supercapacitive performance of the MnMoO4/α-MoO3 composite materials was evaluated using cyclic voltammetry and constant current charge–discharge methods. The synthesis yielded an ideal composite material, with low-resistance MnMoO4 seamlessly integrated with high ion-conductive MoO3. At a current density of 3 A/g, the specific capacitance was measured at 1878.7 F/g, achieving an energy density of 260.9 Wh kg−1 and a power density of 1.448 kW kg−1. The composite materials demonstrated significant potential for the production of high-density supercapacitors. [Display omitted] •Facile synthesis of MnMoO4/MoO3 composite is reported.•A higher specific capacitance of 1878.7F•g−1 for MnMoO4/MoO3 composite at a current density of 3 A•g−1 is achieved.•MnMoO4/MoO3 composite shows promise as candidate for electrochemical storage. In the quest for developing supercapacitors with enhanced energy density, we have successfully synthesized MnMoO4/MoO3 composite materials tailored for supercapacitor applications. The synthesis process utilized (NH4)6Mo7O24·4H2O and MnCl2·4H2O as precursors. The resulting composite materials were thoroughly characterized using a suite of analytical techniques, including scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction analysis, Brunauer-Emmett-Teller surface area measurements, thermogravimetric analysis, and differential scanning calorimetry. Furthermore, the supercapacitive performance of the MnMoO4/α-MoO3 composite materials was evaluated using cyclic voltammetry and constant current charge–discharge methods. The synthesis yielded an ideal composite material, with low-resistance MnMoO4 seamlessly integrated with high ion-conductive MoO3. At a current density of 3 A/g, the specific capacitance was measured at 1878.7 F/g, achieving an energy density of 260.9 Wh kg−1 and a power density of 1.448 kW kg−1. The composite materials demonstrated significant potential for the production of high-density supercapacitors.
ISSN:1387-7003
DOI:10.1016/j.inoche.2024.113481