NiCr2−xGdxO4 ceramics’ magnetic, structural and electrical conductivity as well as their activation energy properties

[Display omitted] •Simple and low cost combustion method.•Materials for applications in the field of energy conversion systems.•Doping not only introduces defects, changes the electronic structure.•The power conversion efficiency of Gd doping effects solar cell performances. The goal of this work is...

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Veröffentlicht in:Inorganic chemistry communications 2024-12, Vol.170, p.113110, Article 113110
Hauptverfasser: Vanasundari, K., Viji, A., Vijayakumar, R., Prakasam, A.
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Sprache:eng
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Zusammenfassung:[Display omitted] •Simple and low cost combustion method.•Materials for applications in the field of energy conversion systems.•Doping not only introduces defects, changes the electronic structure.•The power conversion efficiency of Gd doping effects solar cell performances. The goal of this work is to synthesize and characterize nanoscale nickel chromites nanoparticles doped with Gd using the economical solution combustion method. Numerous analytical techniques, including energy formation, electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction, are used for in-depth characterization. The results show that at low values of coercivity, high values of saturation magnetization, and low values of remnant magnetization, the chromites correspond. The crystalline size of Gd-doped nickel chromites decreases. For the normal spinel structure’s tetrahedral and octahedral coordinated forms, respectively. The present research shows that agglomerated forms and irregular, spherical structures formed by SEM (Scanning Electron Microscope) form regular structures. The present investigation uses a transmission electron microscope (TEM) to illustrate the formation of regular-shaped particles. As demonstrated by Gd-doped NiCr2O4 and pure NiCr2O4, stable interstitial positions are among the typical interstitial positions of the metal oxides. Investigations of magnetic properties from the paramagnetic to the ferromagnetic phase formation. Electrical conductivity and activation energy dropped with Gd doping of nickel chromites and showed an inverse relationship with particle/crystallite sizes. Lastly, applications for NiCr2−x GdxO4 particles were examined and future research directions were also suggested.
ISSN:1387-7003
DOI:10.1016/j.inoche.2024.113110