Luminescence studies and Judd Ofelt parameterization of Dy3+ activated La2(WO4)3 yellow phosphor

[Display omitted] •Dy3+ doped La2(WO4)3 were prepared by microwave assisted co-precipitation method.•Judd Ofelt intensity parameters were calculated and they follow the trend Ω2 > Ω6 > Ω4.•Emission spectra contain peaks due to the transitions 4F9/2 → 6H15/2,13/2.•The optimum concentration of D...

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Veröffentlicht in:Inorganic chemistry communications 2024-07, Vol.165, p.112550, Article 112550
Hauptverfasser: Baby, Bibily, Thomas, Sajan, Jose, Jifi, Thomas, Kukku, Punathil, Prabeesh, Unnikrishnan, N.V., Biju, P.R., Joseph, Cyriac
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Sprache:eng
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Zusammenfassung:[Display omitted] •Dy3+ doped La2(WO4)3 were prepared by microwave assisted co-precipitation method.•Judd Ofelt intensity parameters were calculated and they follow the trend Ω2 > Ω6 > Ω4.•Emission spectra contain peaks due to the transitions 4F9/2 → 6H15/2,13/2.•The optimum concentration of Dy3+ ions in La2(WO4)3 was found to be 10%.•CIE coordinates confirm the suitability of the phosphor for yellow emission. The synthesis and detailed luminescence studies of a series of La2-xDyx(WO4)3 (x = 0.02, 0.1, 0.2, 0.4, 0.6, 0.8) phosphors synthesized via microwave-assisted co-precipitation technique is reported in this paper. The XRD analysis confirmed that the phosphors were crystalized in a monoclinic structure with space group C2/c and FTIR analysis identified the characteristic vibrational modes. Morphological studies were conducted using FESEM analysis, and the EDS technique substantiated the effective incorporation of Dy3+ ions in La2(WO4)3. The photoluminescence excitation and emission spectra of varying concentrations of Dy3+ ions were recorded and an optimum concentration of 10% exhibited the highest intensity. The emission spectra of all phosphors were dominated by peaks at 484 nm and 574 nm. The radiative properties were evaluated using Judd-Ofelt analysis and the JO intensity parameters followed the trend Ω2 > Ω6 > Ω4. The gradual decrease in the decay lifetime value of 4F9/2 excited level with an increase in doping concentration elucidates concentration quenching phenomena due to dipole – quadrupole interaction. The emission data were also analyzed by calculating CIE coordinates and concluded that Dy3+ doped La2(WO4)3 phosphors have potential applications in yellow light generation.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2024.112550