Visible-light driven γ-Al2O3, CuO and γ-Al2O3/CuO nanocatalysts: Synthesis and enhanced photocatalytic activity

[Display omitted] •A facile γ-Al2O3/CuO nanocatalyst were developed via hydrothermal process for enhance photocatalytic activity.•The degradation efficiency achieved to be 91% and 78% decomposition of MB and RhB dyes under visible light irradiation.•The higher photocatalytic performance was obtained...

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Veröffentlicht in:Inorganic chemistry communications 2022-04, Vol.138, p.109311, Article 109311
Hauptverfasser: Sridevi, A., Krishnamohan, S., Thairiyaraja, M., Prakash, B., Yokeshwaran, R.
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Sprache:eng
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Zusammenfassung:[Display omitted] •A facile γ-Al2O3/CuO nanocatalyst were developed via hydrothermal process for enhance photocatalytic activity.•The degradation efficiency achieved to be 91% and 78% decomposition of MB and RhB dyes under visible light irradiation.•The higher photocatalytic performance was obtained due to efficient separation of the photo-induced electron-hole pairs and effective electron–hole generation. A novel and facile γ-Al2O3/CuO nanocomposites (NCS) was fabricated via a hydrothermal technique for Visible light mediated photocatalytic activity. The synthesized samples of pure γ-Al2O3, CuO and γ-Al2O3/CuO NCs were analyzed using XRD, UV-DRS, PL, FT-IR, BET, and FESEM analysis techniques. The as prepared γ-Al2O3, CuO and γ-Al2O3/CuO catalysts were used to degrade Rhodamine B (RhB) and Methylene Blue (MB) textile dyes, which were studied using photocatalytic experiments. The degradation took place in the presence of visible light illumination. The degradation efficiency of γ-Al2O3, CuO, and γ-Al2O3/CuO nanocomposites for RhB and MB dyes was 52 %, 59 %, 78 %, and 65 %, 73 %, 91 %, respectively. The higher degradation efficiency was achieved by using γ-Al2O3/CuO nanocatalysts due to their efficient increase in photo-induced e-/h+ charge separation and diminishes their charge carrier re-coupling factor.
ISSN:1387-7003
1879-0259
DOI:10.1016/j.inoche.2022.109311