Influence of cell temperature on water removal mechanism during shutdown purge in proton exchange membrane fuel cells: Experimental and simulation analysis

The internal temperature of proton exchange membrane fuel cells significantly influences their shutdown purge process a key factor for ensuring operational stability and longevity. This study explores how cell temperature impacts water removal mechanisms during shutdown purge, emphasizing its importance for the operational stability of fuel cell. High-temperature purge experiments were conducted using an integrated stack experimental platform, revealing that prolonged high-temperature purging increased the high frequency resistance of a single cell to 639.44 mΩ∙cm2 and caused severe perforation of the membrane electrode assembly. To delve deeper into the mechanisms of cell temperature influence and the cause of perforation, an isothermal, transient, two-phase flow fuel cell model was developed. The cell temperature during purge was incrementally raised from 303.15 K to 358.15 K in 5 K steps. Detailed analyses of membrane desorption and water phase changes during purge processes were performed. At cell temperatures ranging from 338.15 K to 358.15 K, a 120-s purge reduced the membrane water content to below 4.8, with only a 5 % variation in residual membrane water. When the cell temperature exceeded 323.15 K, water activity increased with temperature, intensifying evaporation and leading to desorption of vapor from the membrane. Consequently, higher temperatures facilitated the removal of liquid water, with no liquid water remaining within cell above 323.15 K. Elevated cell temperatures accelerated the purge, resulting in lower liquid water content and increased vapor, but with minimal difference in membrane water content. The intense evaporation process and rapid purge at high temperatures were identified as direct causes of membrane electrode assembly perforation. This study highlights the critical role of cell temperature in the shutdown purge process, providing innovative insights into optimizing proton exchange membrane fuel cell operations for enhanced performance and durability. •High-temperature purging can lead to membrane over-drying and perforation.•Cell temperature significantly impacts water activity and vapor pressure.•Cell temperature influences the purge rate over residual water content.•Lower cell temperatures result in higher residual water in the membrane.•Low temperatures hinder liquid water removal due to reduced vapor pressure.