Study on the kinetics and reaction mechanism of low-temperature oxidation of lignite with different coalification
•Lignite with different transmittance can be categorized into two types.•The oxidation mechanism of type Ⅰ lignite is –OH, –CH2–, and –CH3 → HO–R–OH → –CHO.•The oxidation mechanism of type Ⅱ lignite is –OH, –CH2–, and –CH3 → –OOH → –COOH.•Different measures against oxidation are required for differe...
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Veröffentlicht in: | Fuel (Guildford) 2025-02, Vol.381, p.133375, Article 133375 |
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Hauptverfasser: | , , , , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •Lignite with different transmittance can be categorized into two types.•The oxidation mechanism of type Ⅰ lignite is –OH, –CH2–, and –CH3 → HO–R–OH → –CHO.•The oxidation mechanism of type Ⅱ lignite is –OH, –CH2–, and –CH3 → –OOH → –COOH.•Different measures against oxidation are required for different type of lignite.
The differences in the coalification of lignite result in noticeable variations in the processes of its low-temperature oxidation. Consequently, this study utilizes thermogravimetric analysis and in-situ FTIR to investigate the oxidation kinetics and reaction mechanisms of lignite with different transmittance (PM). For lignite with PM |
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ISSN: | 0016-2361 |
DOI: | 10.1016/j.fuel.2024.133375 |