Study on the kinetics and reaction mechanism of low-temperature oxidation of lignite with different coalification

•Lignite with different transmittance can be categorized into two types.•The oxidation mechanism of type Ⅰ lignite is –OH, –CH2–, and –CH3 → HO–R–OH → –CHO.•The oxidation mechanism of type Ⅱ lignite is –OH, –CH2–, and –CH3 → –OOH → –COOH.•Different measures against oxidation are required for differe...

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Veröffentlicht in:Fuel (Guildford) 2025-02, Vol.381, p.133375, Article 133375
Hauptverfasser: Zhao, Jianqiao, Wei, Zheng, Shi, Chang, Meng, En, Gu, Bingchen, Li, Ning, Yu, Shi, Meng, Xianliang, Chu, Ruizhi, Wu, Guoguang, Jiang, Xiaofeng, Li, Xiao, Li, Weisong, Wan, Yongzhou
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Sprache:eng
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Zusammenfassung:•Lignite with different transmittance can be categorized into two types.•The oxidation mechanism of type Ⅰ lignite is –OH, –CH2–, and –CH3 → HO–R–OH → –CHO.•The oxidation mechanism of type Ⅱ lignite is –OH, –CH2–, and –CH3 → –OOH → –COOH.•Different measures against oxidation are required for different type of lignite. The differences in the coalification of lignite result in noticeable variations in the processes of its low-temperature oxidation. Consequently, this study utilizes thermogravimetric analysis and in-situ FTIR to investigate the oxidation kinetics and reaction mechanisms of lignite with different transmittance (PM). For lignite with PM 
ISSN:0016-2361
DOI:10.1016/j.fuel.2024.133375