Dew pressure point and liquid dropout of CH4 + alcohol (methanol or ethanol) system with high gas content at high-pressure and high-temperature
•Experimental measurements VL phase equilibria are presented.•Dew pressure and liquid dropout data for methane + alcohol (methanol or ethanol).•Higher liquid dropout values for methane + ethanol system.•Thermodynamic modelling by using CPA equation of state. Hydrate inhibitor injection through gas-l...
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Veröffentlicht in: | Fluid phase equilibria 2023-10, Vol.573, p.113873, Article 113873 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •Experimental measurements VL phase equilibria are presented.•Dew pressure and liquid dropout data for methane + alcohol (methanol or ethanol).•Higher liquid dropout values for methane + ethanol system.•Thermodynamic modelling by using CPA equation of state.
Hydrate inhibitor injection through gas-lift flow is used in production fields. The gas + inhibitor system's phase behavior provides essential information regarding monophasic regions and operational safety conditions. Methane is the main constituent of natural gas and is commonly used as a model component to represent gas reservoir fluids. However, pressure variation during a gas-lift injection can cause liquid dropout at valve injection. Therefore, phase behavior knowledge of methane + alcohol mixtures is potentially interesting in the oil and gas industry. In this work, dew pressure and liquid dropout data were experimental measured for methane + methanol (96.60 mol % CH4) and methane + ethanol (96.50 mol % CH4) systems in the temperature domain of 313.15 to 366.65 K and pressure up to 70 MPa. The CPA equation of state was used to correlate dew pressure and liquid dropout data for all systems, presenting a dew pressure absolute relative deviation of 6.89 and 5.22 % for methane + methanol (96.60 mol % CH4) and methane + ethanol (96.50 mol % CH4), respectively.
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ISSN: | 0378-3812 1879-0224 |
DOI: | 10.1016/j.fluid.2023.113873 |