Vapor-liquid equilibria (VLE) of the binary mixture of normal hexane and water at P = 2.5 MPa and T=(456.85 – 487.85 K)

•A VLE study on C6/H2O at T = 183.7–214.7 °C and at P = 2.5 MPa is reported.•VLE results are presented in a T-xy diagram.•Azeotropic co-condensation at 183.7 °C and xC6=0.6029 was observed.•VLE data were modeled by CPA EoS and NRTL model.•Activity coefficient and infinite dilution activity coefficient are estimated. We report the vapor-liquid equilibria (VLE) of the binary mixture of the n-C6/H2O system at P=2.5 MPa and T=(456.85 – 487.85 K). The result showed an azeotropic behavior with a co-condensation temperature of ∼456.85 K at an n-C6 mole fraction of ∼0.6029. The measured experimental data are modeled with the Cubic Plus Association Equation of State (CPA-EoS) and activity coefficient-based Non-Random Two Liquid (NRTL) model. The infinite dilution activity coefficient of n-C6 and H2O are also estimated over the temperature range of interest. The overall root mean square deviation (RMSD) of the n-C6 mole-fraction in vapor and liquid phases for the CPA EoS and NRTL models are 0.0370 and 0.0765, respectively. [Display omitted]