Measurement and correlation of ternary system {water + 2,3-butanediol + 2-methyl-1-pentanol} and {water + 2,3-butanediol + 3-methyl-1-butanol} liquid-liquid equilibrium data

The liquid–liquid equilibriums (LLE) in two ternary systems, {water + 2,3-butanediol + 2-methyl-1-pentanol} and {water + 2,3-butanediol + 3-methyl-1-butanol}, were studied at three temperatures, 298.2 K, 308.2 K, and 318.2 K. To complete the phase diagram, the LLE data and solubility data were obtai...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Fluid phase equilibria 2020-08, Vol.518, p.112639, Article 112639
Hauptverfasser: Kim, Hyun Ji, Yim, Joon-Hyuk, Lim, Jong Sung
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The liquid–liquid equilibriums (LLE) in two ternary systems, {water + 2,3-butanediol + 2-methyl-1-pentanol} and {water + 2,3-butanediol + 3-methyl-1-butanol}, were studied at three temperatures, 298.2 K, 308.2 K, and 318.2 K. To complete the phase diagram, the LLE data and solubility data were obtained. To select a suitable solvent, distribution coefficient (D) and selectivity (S) were calculated. The values of D and S of 2-methyl-1-pentanol were (0.36–0.67) and (3.29–7.97) and those of 3-methyl-1-butanol were (0.44–0.95) and (2.29–5.80), respectively. Compared to the values of previously reported solvents, the values of D and S of 3-methyl-1-butanol were relatively higher. Nonrandom two liquids (NRTL) model was used to correlate the experimental data. All root mean square deviation (RMSD) values were 0.0166 in average, which indicates successful correlations between the experimental data and those obtained from the NRTL model.
ISSN:0378-3812
1879-0224
DOI:10.1016/j.fluid.2020.112639