Hydrothermal alteration associated with the Chicxulub impact crater upper peak-ring breccias

•The Chicxulub impact generated a widespread hydrothermal system that affected the peak-ring.•Peak hydrothermal temperatures recorded in the upper peak-ring impact melt-bearing breccias are ∼350°C.•Predominant alteration assemblages consist of alkali feldspars, zeolites, Fe-Mg clays and carbonates. The 66 Ma, ∼180 km Chicxulub impact structure in the northern Yucatán peninsula and southern Gulf of Mexico is the best-preserved large impact crater on Earth with a well-developed peak ring. The most recent drilling campaign took place offshore during the joint International Ocean Discovery Program – International Continental Scientific Drilling Program (IODP–ICDP) Expedition 364 at site M0077A (21.45°N, 89.95°W) and recovered ∼830 m of continuous core. Initial examination revealed that the peak-ring comprises four main lithological units (from the base upwards): crystalline basement granitoid rocks (Unit 4); a thin layer of impact melt rocks (Units 3A and B); melt-bearing breccias (Units 2A–C); and post-impact sedimentary rocks (Unit 1). Preliminary analysis of the drill core indicated that hydrothermal alteration has affected all lithologies and is especially pervasive in the melt-bearing breccias of Unit 2 (721.6 to 617.33 meters below sea floor, mbsf). Here we present the first detailed investigation of hydrothermal alteration within the melt-bearing breccias. Alteration phases are predominantly Fe-Mg clay minerals, zeolites, alkali feldspars, calcite and minor sulfides, sulfates, opal and Fe-Ti oxides. Alteration is especially intense proximal to lithologic contacts, particularly at the base of subunit 2B where there is an abrupt increase in host rock porosity ∼30 m above the impact melt rocks. The pervasiveness of clay minerals and zeolites is attributed to the high amounts of devitrified silicate glass throughout Unit 2. The phases preserved here are consistent with the findings of previous hydrothermal studies in other areas of the Chicxulub structure, and suggest an evolving water-rock system that was alkaline-saline, comparable to seawater-volcanic glass alteration.