Transport of coexisting Ni-Cu sulfide liquid and silicate melt in partially molten peridotite

•Imaged sulfide-bearing partially molten peridotite using X-ray microtomography.•Sulfide was stranded in locally connected melt networks under static conditions.•Shear stress produced the alignment of elongated silicate melt and sulfide pockets.•Liquid alignment oriented at 10–20° to shear plane, hu...

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Veröffentlicht in:Earth and planetary science letters 2020-04, Vol.536, p.116162, Article 116162
Hauptverfasser: Wang, Zhenjiang, Jin, Zhenmin, Mungall, James E., Xiao, Xianghui
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Sprache:eng
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Zusammenfassung:•Imaged sulfide-bearing partially molten peridotite using X-ray microtomography.•Sulfide was stranded in locally connected melt networks under static conditions.•Shear stress produced the alignment of elongated silicate melt and sulfide pockets.•Liquid alignment oriented at 10–20° to shear plane, hundreds of microns in length.•Silicate melt provides efficient transport pathway for sulfide driven by stress. Transport of coexisting sulfide and silicate melts in partially molten peridotite contributes to the redistribution of chalcophile elements within the upper mantle as well as the genesis of magmatic Ni-Cu sulfide deposits, but has not been investigated systematically. Using laboratory experiments, theoretical calculations, and X-ray synchrotron microtomography, this study documents the topology and considers controls on the extraction of two immiscible liquids during partial melting of mantle peridotite. Under hydrostatic conditions, the measured dihedral angle at silicate melt-mineral-mineral junctions is 13.7–21.3°. Silicate melt is distributed along grain edges forming incompletely interconnected melt channels that disconnected by some dead ends at melt fractions ∼7–9 vol%. Application of theoretically predicted permeability (k∼10−14–10−16 m2) permits estimation of the extraction velocity of silicate melt of 0.7-11.1 μm/day within a single interconnected melt channel. In the absence of silicate melt, isolated sulfide droplets (3.77 vol%) show a sulfide-olivine-olivine dihedral angle of 91.5–101.3°. However, in the presence of silicate melt, sulfide droplets (average size ∼2.53 ± 2.14 μm, 1σ) are partially surrounded by silicate melt and stranded in triple junctions or melt pockets due to the limitation of the smallest dimension (0.3 μm) of melt channels. Thus, the extraction of sulfide liquid is highly restricted by these dead ends and the smallest dimension of melt channels during porous flow of silicate melt. In contrast, during large-strain shear deformation (strain ∼1.6–2.5), initially stranded sulfide droplets were elongated and extracted with silicate melt into liquid-rich sheets with a length of several hundred microns, constantly oriented at 14.3 ± 4.5° to the shear plane and antithetic to the shear direction. The angle is lower than that (18–30°) of those sheets containing sulfide liquid only, indicating that silicate melt dominates liquid-rich sheets. Driven by stress, silicate melt-dominated liquid-rich sheets open the appropriately oriente
ISSN:0012-821X
1385-013X
DOI:10.1016/j.epsl.2020.116162