Tuning of (E)-(4-fluorophenyl)-1,1-diamino-2,3-diazabuta-1,3-diene nanostructures for the selective detection of imidacloprid

The present work demonstrates a facile route for synthesizing the organic nanoparticles (ONPs) and the blue fluorescent Quantum Dots (QDs) based on an organic molecule named (E)-(4-fluorophenyl)-1,1-diamino-2,3-diazabuta-1,3-diene. The synthesis process possesses advantages viz green synthesis, non-toxic degraded products, and amount of organic compound. Initially, the ONPs were prepared using the nanoprecipitation method and were screened for their recognition potential against various pesticides, however, no selectivity has been observed. This motivated us to tune the ONPs into QDs. The QDs were prepared using the hydrothermal method and a color change was observed in the QDs solution under daylight and under a UV lamp. The emission wavelength was observed at 400 nm (λexcitation = 278 nm). The synthesized QDs exhibited selective sensing potential towards imidacloprid via a quenching mechanism. A normalised decrement in the luminescence intensity of QDs was observed on raising the concentration of imidacloprid and a good linear response was noticed over a concentration varies from 1 μM to 100 μM with a regression coefficient of 0.99. The detection limit was estimated to be 4.53 nM and quantification limit was calculated to be and 13.72 nM. [Display omitted] •The green synthesis of nanostructures (ONPs and QDs) of (E)-(4-fluorophenyl)-1,1-diamino-2,3-diazabuta-1,3-diene was performed.•The selective detector for imidacloprid, a extensively used neonicotinoid pesticide was found.•The LOD and LOQ were estimated to be 4.53 nM and 13.72 nM respectively.•The work developed an enzyme free approach for imidacloprid detection.•The TD-DFT study was performed in order to predict the detection mechanism.