Molecularly imprinted polymer-based photocatalyst for highly selective degradation of methylene blue
ZnO quantum dots were synthesized by chemical precipitation, CuFe2O4 nanoparticles were prepared by in situ synthesis of cellulose, and then ZnO/CuFe2O4 (ZCF) composites were fabricated. A photocatalyst (ZCF@MB-MIP) with specific molecule recognition and photocatalytic degradation characteristics wa...
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Veröffentlicht in: | Environmental research 2021-03, Vol.194, p.110684, Article 110684 |
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Sprache: | eng |
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Zusammenfassung: | ZnO quantum dots were synthesized by chemical precipitation, CuFe2O4 nanoparticles were prepared by in situ synthesis of cellulose, and then ZnO/CuFe2O4 (ZCF) composites were fabricated. A photocatalyst (ZCF@MB-MIP) with specific molecule recognition and photocatalytic degradation characteristics was then produced by a surface imprinting method using methylene blue (MB) as the template molecule. The structure of ZCF@MB-MIP was characterized by Fourier transform infrared spectroscopy, transmission electron microscopy and X-ray diffraction. The photocatalytic efficiency of ZCF@MB-MIP and its specific recognition performance in MB degradation was analyzed. The adsorption kinetics of MB by ZCF@MB-MIP conformed to the quasi-secondary adsorption kinetics model. ZCF@MB-MIP displayed effective photocatalytic degradation of MB under natural light. The degradation rate reached 95.8%, which was much higher than those of ZCF, CuFe2O4 nanoparticles, and a non-imprinted reference sample under the same conditions. This work is a useful reference for the construction of photocatalysts that show highly selective recognition of dye molecules.
A novel molecularly imprinted catalyst was prepared and its fluorescence characteristics were studied. [Display omitted] |
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ISSN: | 0013-9351 1096-0953 |
DOI: | 10.1016/j.envres.2020.110684 |