Comparative removal of As(V) and Sb(V) from aqueous solution by sulfide-modified α-FeOOH

Efficient elimination of As(V) and Sb(V) from wastewater streams has long been a major challenge. Herein, sulfide-modified α-FeOOH adsorbent was fabricated via a simple sulfidation reaction for removing As(V) and Sb(V) from aqueous media. Compared with the pristine α-FeOOH, sulfide-modified α-FeOOH increased the adsorption of As(V) from 153.8 to 384.6 mg/g, and Sb(V) adsorption from 277.8 to 1111.1 mg/g. The enhanced adsorption of both As(V) and Sb(V) was maintained at the pH range from 2 to 11, and was not interfered by various coexisting anions such as Cl−, SO42−, NO3−, SiO32− and PO43−. The adsorption affinity increased from 0.0047 to 0.0915 and 0.0053 to 0.4091 for As(V) and Sb(V), respectively. X-ray photoelectron spectroscopic investigation demonstrated a reductive conversion of As(V) to As(III) during the adsorption process with sulfide-modified α-FeOOH, but with no obvious variation of Sb(V) speciation. While the removal mechanism for As(V) was reduction followed by adsorption via hydroxyl groups, mainly surface complexation was involved in the removal of Sb(V). This study presented a simple strategy to enhance the adsorption capacity and adsorption affinity of α-FeOOH toward As(V)/Sb(V) via sulfide-modification. [Display omitted] •Sulfide-modified α-FeOOH was synthesized for As(V) and Sb(V) removal.•As(V)/Sb(V) adsorption capacity and affinity were remarkably improved.•Enhanced removal was maintained at pH range from 2 to 11.•Reduction of As(V) to As(III) followed by adsorption was observed.•Removal was not affected by the presence of coexisting anions. Capsule: Sulfide-modified α-FeOOH remediates both low and high arsenic/antimony levels under varying pH and competitive anions – conditions common in wastewater.