Effects of CO2-saturated brine imbibition on the mechanical and seepage characteristics of Longmaxi shale

Supercritical carbon dioxide (SC– CO2) serves as a promising anhydrous fracturing fluid that has the potential to simultaneously enhance shale gas recovery and accomplish CO2 sequestration within shale reservoirs. However, the hydromechanical properties of shale are considerably affected by CO2-brine-shale interaction. This study conducted shale imbibition experiments involving subcritical/supercritical CO2 saturated brine (Sub/SC-CO2+brine). Triaxial compressive strength tests were performed to evaluate the impact of Sub/SC-CO2+brine imbibition on the mechanical properties of shale, as well as the influence of SC-CO2+brine imbibition on shale permeability. The results indicate that, after SC-CO2 brine imbibition, noticeable macroscopic cracks are formed parallel to the bedding plane. The imbibition of Sub/SC-CO2+brine results in the reduction in axial stress and Young's modulus, while simultaneously increasing the axial strain of shales. Compared to Sub-CO2+brine, SC-CO2+brine exhibits a higher imbibition pressure and a more intense geochemical reaction with shale. Due to increased compressibility sensitivity, the averaged permeability after SC-CO2+brine imbibition shows a reduction of nearly 70 % compared to that before imbibition. The insights from this research are expected to provide theoretical support for shale gas recovery and CO2 geological sequestration. •The effects of Sub/SC-CO2+brine imbibition on the mechanical properties of shale were investigated.•Compared to SC-CO2 +brine imbibition, Sub-CO2+brine imbibition induced higher axial stress and lower axial strain.•The permeability reduced by more than an order of magnitude due to SC-CO2+brine imbibition.