Facile and efficient fabrication of Cu1.04Mn0.96O2 nanosheet anodes with superior electrochemical lithium storage capability

[Display omitted] •The nanosheet structure provides more active sites and shortens the transport path of Li+ and electrons.•Cu partial substitution for Mn may enhance the structural stability.•Cu1.04Mn0.96O2 binary metal oxides improve capacity through abundant redox reaction pathways. In this work,...

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Veröffentlicht in:Chemical physics letters 2024-10, Vol.853, p.141525, Article 141525
Hauptverfasser: Ye, Mingyuan, Zhao, Ziqi, Liu, Liying, Shao, Li, Liu, Li, Hao, Xiaorui, Lv, Jiaqi, Wang, Peng-Fei, Zhang, Yu-Hang, Shi, Fa-Nian, Wu, Yuhan
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Sprache:eng
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Zusammenfassung:[Display omitted] •The nanosheet structure provides more active sites and shortens the transport path of Li+ and electrons.•Cu partial substitution for Mn may enhance the structural stability.•Cu1.04Mn0.96O2 binary metal oxides improve capacity through abundant redox reaction pathways. In this work, Cu1.04Mn0.96O2 nanosheets were synthesized via a simple hydrothermal method, and their electrochemical lithium storage properties and reaction mechanisms were investigated. The nanosheet structure effectively promotes electron transfer and shortens the transport path. Additionally, the partial substitution of Cu for Mn decreases the Jahn-Teller distortion of the MnO6 octahedron. Employing as an anode for Li-ion batteries, the specific capacity reached 610.91 mAh g−1 after 100 cycles at a current density of 100 mA g−1.
ISSN:0009-2614
DOI:10.1016/j.cplett.2024.141525