Effect of hydrochloric acid on the properties of Ni-MOF nanostructures as supercapacitor electrode materials

•The specific surface area of the organic framework affects the electrochemical properties.•Ni-MOF has excellent electrochemical properties.•The acid-base environment affects the growth of the organometallic framework materials.•The highest specific capacitance of the prepared sample was 2567.23 F/g...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical physics letters 2024-09, Vol.850, p.141474, Article 141474
Hauptverfasser: Liu, R., Shang, M.Y., Liu, C., Hao, Y., Yang, F., Shi, J.Y., Chen, Y., Wang, Y.F., Feng, J.Q., Yang, P.F., Lu, P.A.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•The specific surface area of the organic framework affects the electrochemical properties.•Ni-MOF has excellent electrochemical properties.•The acid-base environment affects the growth of the organometallic framework materials.•The highest specific capacitance of the prepared sample was 2567.23 F/g. In this paper, we investigate the effect of hydrochloric acid on the energy storage characteristics of nickel-based metal–organic framework (Ni-MOF) nanostructures. Electrochemical tests reveal that Ni-MOF exhibit high capacitance under hydrochloric acid regulation, achieving a current density of 2567.23 F/g at 2 A/g in 1 ml. Additionally, the synthesized Ni-MOF demonstrate low electrical resistance, with a resistance (Rs) of 1.209 Ω at a hydrochloric acid volume of 1 ml. After 5000 cycles of galvanostatic charge–discharge testing, the cycle retention efficiency of Ni-MOF-0.5 ml remains at 85.71 %.
ISSN:0009-2614
1873-4448
DOI:10.1016/j.cplett.2024.141474