Enhancing the electrical conductivity of concrete using metal-organic frameworks

This research evaluates the electrical conductivity, mechanical characteristics, durability, and environmental viability of electrically conductive concrete (ECC) incorporating zeolitic imidazolate framework (ZIF-67) metal-organic-framework (MOF). Performance of MOF-ECC was characterized by slump, e...

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Veröffentlicht in:Construction & building materials 2024-04, Vol.425, p.136061, Article 136061
Hauptverfasser: El-Mir, Abdulkader, Najm, Omar, El-Hassan, Hilal, El-Dieb, Amr, Alzamly, Ahmed
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Sprache:eng
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Zusammenfassung:This research evaluates the electrical conductivity, mechanical characteristics, durability, and environmental viability of electrically conductive concrete (ECC) incorporating zeolitic imidazolate framework (ZIF-67) metal-organic-framework (MOF). Performance of MOF-ECC was characterized by slump, electrical conductivity/resistivity, compressive strength, water absorption, volume of permeable pore voids, and economic and environmental viability. Its performance was compared to plain concrete and counterparts made with different conductive materials, namely steel fibers, carbon fibers, graphite powder, and carbon black. Results showed that increasing the volumetric rate of conductive materials reduced the slump and required more superplasticizer to maintain consistency. Meanwhile, the addition of MOF led to equivalent or more electrically concrete compared to other materials. Compressive strength and water absorption were affected by the type and proportion of conductive material but were positively impacted by MOF incorporation. A performance index, involving electrical resistivity, mechanical characteristics, durability, and environmental viability, highlighted that ECC containing 0.5% MOF by volume was most suitable for multifunctional concrete applications. •Metal organic framework (MOF) ZIF-67 was employed to produce electrically conductive concrete.•The effect of MOF ZIF-67 on the performance of concrete was compared to that of other conductive materials.•MOF ZIF-67 was more effective in enhancing the electrical conductivity of concrete than other powder materials.•Mechanical and durability properties were improved upon incorporating MOF ZIF-67 to concrete.•TOPSIS integration showed that MOF ZIF-67 was the most suitable conductive material at a volume fraction of 0.5%.
ISSN:0950-0618
1879-0526
DOI:10.1016/j.conbuildmat.2024.136061