Role of silica fume on hydration and strength development of ultra-high performance concrete

•A new method to investigate the influence of silica fume on UHPC is proposed.•Effect of silica fume on early hydration of UHPC is carefully investigated.•Strengthening mechanism of silica fume on microstructure and compressive strength development of UHPC is clarified. Silica fume (SF) is the most commonly used ingredient in ultra-high performance concrete (UHPC) due to its inherited properties, which can effectively improve the rheology and mechanical performance. However, investigations with regard to its filler effect and pozzolanic reaction on UHPC are limited. To assess the contribution from SF, a chemically inert filler of titanium dioxide (TD), with a comparable particle size distribution and specific surface area (per unit volume), was selected as a reference ingredient to eliminate the influence of packing effect. Results showed the addition of SF will accerate the early hydation of UHPC and it is controlled by the combined effect of seeding effect and preferential adsorption. Moreover, the SF’s surface characteristic controlling the concentration of adsorption sites provided for hydration product is the key factor influencing the early hydration rather than surface specific area. Furthermore, the enhancement of compressive strength of UHPC after 3 days is attributed to the pozzolanic reaction of SF and its promoting effect on cement hydration degree. The total contribution is less than 20%, and it will enhances with the decrease of W/C ratio.