Hygrothermal durability of epoxy adhesives used in civil structural applications

Adhesive durability and joint reliability, strictly related to the bonding agents, are key parameters still under evaluation in civil as well as in other engineering fields. Moisture, different environmental agents and temperature (in particular) can strongly affect the performance of the adhesive joints over the time limiting their applicability. The environmental temperature may exceed the glass transition temperature (Tg) of the adhesive formulation entailing relevant changes in its properties, determining, for instance, a transition from a hard to a rubbery behaviour, thus compromising its specific application. Furthermore, due to changes of the temperature values, the structural adhesive can be naturally subjected to a delay or increase in the curing degree. Hence adverse or positive changes in strength and stiffness can be manifested. Within this framework, the topic of the present paper is the study of the hygro-thermal durability of two commercial epoxy resins, suitable for civil engineering applications, respect to the immersion in tap water and sea water for a period of fifteen months at the temperature of 30 °C. To this scope a wide experimental program was developed comprising both End Notch Failure (ENF) tests on the adhesive samples (adherent in glass fiber reinforced polymer, GFRP) for evaluating the pure fracture energy in Mode II of the resins and the water absorption tests for resins and GFRP materials. In general, the results, in terms of fracture energy, show an initial increment (first three-four months) followed by a decrement up to the reaching of a plateau (in the ninth-twelfth month of conditioning). For what concerns the water absorption, the results show that the equilibrium value of both resins is reached in about one month, while that of GFRP samples depend on the type of liquid: three months for tap water and about five months for sea water. Considering the lower activity of the seawater, the longer time to reach the equilibrium value was an expected result.