Solvent-responsive switching wettability of superoleophobic/superhydrophilic quartz sand filter medium facilitates rapidly oil/water separation and demulsification

Oil-spill accidents occur frequently, and the oil pollution caused by oil spills is attracting extensive attention from all circles of society. To resolve this problem, solvent-responsive superoleophobic/superhydrophilic quartz sand (SSQS) was manufactured by introducing ZnO nanoparticles, short-chain fluorinated compounds, and hydrophilic-induced units into the surface of quartz sand. Experimental results showed that SSQS can reversibly convert the superoleophobic/superhydrophilic surfaces into superoleophilic/underoil superhydrophobic surfaces within 10 s. The solvent-responsive surface of SSQS demonstrated selective separation performance for mixtures of oil/water and various surfactant-stabilized oil-in-water emulsions and water-in-oil emulsions before and after wettability conversion. Oil/water solutions were separated synchronously and continuously using the "┴" type of oil/water separating system, with a separation efficiencies of 99.33 % at high flux. After ten runs of the wettability transition, the oil/water mixture's separation efficiency remained over 99 %. More importantly, SSQS can accomplish the on-demand, gravity-driven demulsification and separation of oil/water emulsions with excellent separation efficiency and flux. The directional migration of oil droplets on the SSQS surface could possibly be described by the wetting performance of oil phase on the special wettability surface, and the solvent-responsive wettability transition of the SSQS surface. SSQS also exhibited brilliant mechanical durability, anticorrosion ability, and wetting stability under severe conditions. Therefore, this work provided a new research direction for the reversible wettability transition of granular filter media. [Display omitted]