Roll-to roll initiated chemical vapor deposition of super hydrophobic thin films on large-scale flexible substrates
[Display omitted] •A roll-to-roll iCVD system was designed.•Superhydrophobic coatings were deposited on bamboo surfaces.•High roll speeds up to 225 mm/min was achieved.•As-deposited polymers were conformal and uniform. In this study, a large-scale roll-to-roll initiated chemical vapor deposition (iC...
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Veröffentlicht in: | Chemical engineering science 2020-04, Vol.215, p.115466, Article 115466 |
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Format: | Artikel |
Sprache: | eng |
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•A roll-to-roll iCVD system was designed.•Superhydrophobic coatings were deposited on bamboo surfaces.•High roll speeds up to 225 mm/min was achieved.•As-deposited polymers were conformal and uniform.
In this study, a large-scale roll-to-roll initiated chemical vapor deposition (iCVD) system was developed to allow for coating superhydrophobic thin films on flexible substrates. Poly(hexafluorobutyl acrylate), which possesses a short fluorinated side-chain, was chosen as the hydrophobic finish material, while a commercial porous bamboo fabric was used as the flexible substrate. After iCVD coating, bamboo surface, which is superhydrophilic by its nature, transformed into a superhydrophobic with a water contact angle of 156° without changing its porous and flexible structure. Similar hydrophobic properties were observed against various daily liquids. Complete coverage of as-deposited films on both sides of bamboo surfaces was observed at very high roll speeds up to 225 mm/min, which allow coatings on 20 m2 flexible substrates in a single run. Large scale contact angle and chemical uniformity of coatings on fabric surfaces were evaluated using contact angle and XPS analyses. |
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ISSN: | 0009-2509 1873-4405 |
DOI: | 10.1016/j.ces.2019.115466 |