Invariant expressions for linear complex mechanisms: Generalization for polar two-step sub-mechanisms

•A new linear sub-mechanism is characterized: the polar two-step sub-mechanism.•This two-step sub-mechanism can be identified within a complex linear mechanism.•Invariant expressions were obtained for the polar two-step sub-mechanism.•These invariant expressions are identical to those obtained from...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical engineering science 2020-01, Vol.211, p.115291, Article 115291
Hauptverfasser: Branco, D., Yablonsky, G.S., Marin, G.B., Constales, D.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:•A new linear sub-mechanism is characterized: the polar two-step sub-mechanism.•This two-step sub-mechanism can be identified within a complex linear mechanism.•Invariant expressions were obtained for the polar two-step sub-mechanism.•These invariant expressions are identical to those obtained from a two-step mechanism.•A mathematical demonstration of this feature is presented. We generalize the results on invariances found for linear two-step mechanism within our approach to joint kinetics. It is demonstrated that similar invariances can be formulated for complex linear mechanisms if within these mechanisms there is a specific sub-mechanism, i.e. a so-called polar two-step sub-mechanism involving A ⇄ B ⇄ C where B can be part of a linear sub-mechanism not otherwise involving the poles A and C.
ISSN:0009-2509
1873-4405
DOI:10.1016/j.ces.2019.115291