Invariant expressions for linear complex mechanisms: Generalization for polar two-step sub-mechanisms
•A new linear sub-mechanism is characterized: the polar two-step sub-mechanism.•This two-step sub-mechanism can be identified within a complex linear mechanism.•Invariant expressions were obtained for the polar two-step sub-mechanism.•These invariant expressions are identical to those obtained from...
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Veröffentlicht in: | Chemical engineering science 2020-01, Vol.211, p.115291, Article 115291 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | •A new linear sub-mechanism is characterized: the polar two-step sub-mechanism.•This two-step sub-mechanism can be identified within a complex linear mechanism.•Invariant expressions were obtained for the polar two-step sub-mechanism.•These invariant expressions are identical to those obtained from a two-step mechanism.•A mathematical demonstration of this feature is presented.
We generalize the results on invariances found for linear two-step mechanism within our approach to joint kinetics. It is demonstrated that similar invariances can be formulated for complex linear mechanisms if within these mechanisms there is a specific sub-mechanism, i.e. a so-called polar two-step sub-mechanism involving A ⇄ B ⇄ C where B can be part of a linear sub-mechanism not otherwise involving the poles A and C. |
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ISSN: | 0009-2509 1873-4405 |
DOI: | 10.1016/j.ces.2019.115291 |