Simultaneous realization of efficient solar evaporation and electricity collection through dual regulation of chemical composition and pore channels

•Developed a solar evaporator with both low latent heat and power generation.•The evaporation rate is up to 3.70 kg m−2h−1, and latent heat is low as 924 kJ kg−1.•The evaporator demonstrates a sustained open-circuit voltage for over 7 h, stabilizing at ∼270 mV.•The evaporator exhibits exceptional desalination capabilities and effective antimicrobial properties. The solar-driven interfacial evaporation is a recently developed zero-energy technology for seawater desalination. However, the low evaporation rate poses a significant obstacle to its industrial application, and the collection of streaming potential formed during the evaporation process remains challenging. In this paper, we constructed a solar evaporator capable of simultaneously achieving efficient solar evaporation and electricity collection. Specifically, a double network structure hydrogel comprising polyvinyl alcohol (PVA) and TEMPO-oxidized cellulose nanoparticles nanofibers (TOCNFs) was fabricated using ice templating, with the addition of sodium lignosulfonate (SLS) to further modulate water distribution within the network. The incorporation of carbon nanotubes (CNTs) enabled the achievement of a PVA/TOCNFs/SLS (PTFS) gel-based solar evaporator. The strong electronegativity carried by the TOCNFs enhances the electrostatic repulsion in the PVA-TOCNFs network, thus improving the mechanical properties of PTFS evaporator. The introduction of SLS, which contains abundant sulfonate groups, provides certain antibacterial properties to PTFS evaporator. Due to the presence of numerous hydrophilic groups, both TOCNFs and SLS can form weak hydrogen bonds with water. Through the synergistic effect of TOCNFs and SLS, the latent heat of water in PTFS evaporator is reduced to 924 kJ kg−1, enabling an evaporation rate of 3.70 kg m−2h−1 under 1 sun irradiation. Owing to the smaller pore size relative to the Debye radius and the presence of electronegative functional groups within the pores of PTFS evaporators, an overlapping bilayer is formed when water flows through, resulting in an open-circuit voltage increase of up to 270 mV. The integration of high-efficiency solar evaporation with streaming potential collection presents a novel avenue for enhancing the utilization of solar energy.