Experimental and computational (Chemical Kinetic + CFD) analyses of Self-Recuperative annular tubular porous burner for NH3/CH4 -air Non-Premixed combustion
•Fuel gets consumed much earlier in a porous combustor compared to the dumb combustor.•Emissions are lower for the stacks of 10+20 PPI compared to the stacks of 10 PPI.•Combustion efficiency is higher for 10+20 PPI stacks compared to 10 PPI stacks.•Combustor exit temperature is lower in 10+20 PPI st...
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Veröffentlicht in: | Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2024-02, Vol.481, p.148439, Article 148439 |
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Sprache: | eng |
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Zusammenfassung: | •Fuel gets consumed much earlier in a porous combustor compared to the dumb combustor.•Emissions are lower for the stacks of 10+20 PPI compared to the stacks of 10 PPI.•Combustion efficiency is higher for 10+20 PPI stacks compared to 10 PPI stacks.•Combustor exit temperature is lower in 10+20 PPI stacks compared to 10 PPI stacks.
Ammonia is now being explored as a potential gas turbine fuel because of its renewable and carbon-free nature. Ammonia combustion possesses various limitations, such as high NO emissions, low burning velocity, and high auto-ignition temperature. Moreover, dual-fuel combustion approaches can be used to mitigate these drawbacks. However, the limitations of available information about the resulting emissions are insufficient to encourage widespread adoption. In this work, an NH3/CH4-air fueled self-recuperative high aspect ratio annular tubular porous burner is developed for gas turbine power applications. In this burner, an annular zone surrounds the combustion chamber to preheat the incoming air, while two perforated discs are mounted between the combustor and annular zone for uniform distribution of air. Eight Zirconia foams (4 of 10 PPI and 4 of 20 PPI) are stacked at the upstream side of the combustor. Experimentally, air preheat temperature, combustor exit temperature, NO, and CO emissions are analyzed and measured for various ammonia addition (0–41 % by weight) percentages, equivalence ratio of 1.0, and heat inputs of 17 & 21 kW for 10 PPI and a combination of 10 and 20 PPI porous foams. A preheated air stream coming from the annular zone speeds up fuel dissociation and helps in stabilizing the flame on the upstream side of the combustor. Combustor exit temperatures are lower in sandwich cases of 10 + 20 PPI than the porous foams of 10 PPI. However, with porous foams of 10 PPI, the air preheat temperature is higher. The insertion of porous foams shows better recirculation of heat and stable combustion is observed for higher percentages of ammonia and higher thermal inputs. The OH radicals are distributed for larger areas inside the dumb combustor, while for porous combustion, it is distributed near the porous foams. The porous sandwich cases of 10 + 20 PPI shows higher combustion efficiency compared to 10 PPI and without porous cases. The chemical kinetic analysis shows that the HNO and HCO radicals act as the main intermediate channel for NO and CO production. |
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ISSN: | 1385-8947 1873-3212 |
DOI: | 10.1016/j.cej.2023.148439 |