Endowing versatility and superamphiphobicity to composite coating via a bioinspired strategy

[Display omitted] •A versatile and superamphiphobic PVDF/F-HGM@SiO2/F-SiO2 coating was fabricated via a bioinspired strategy.•A micro-/nano-/nano-hierarchical structure was constructed on the coating surface.•The coating exhibited outstanding crude-oil-repellency and anti-waxing deposition properties.•The liquid-repellency and anti-waxing mechanisms were proposed. The strong adhesion by crude oil and the deposition of wax in petrochemical pipeline systems are notorious problems, which seriously threaten the safety and economic production of the petroleum industry. Superamphiphobic coatings that repel water/oil offer exciting opportunities to solve these problems, but there are formidable challenges in developing elaborate structures facilely. Herein, a springtail-inspired and multifunctional superamphiphobic coating (OCA = 152.1 ± 0.4°, OSA = 8.2 ± 0.8°) was prepared by a straightforward spraying technique. To emulate the cuticular characteristics of the springtail, the micro-/nano-hierarchical fillers prepared by loading silica nanoparticles on the surface of hollow glass microspheres and then chemical modification (F-HGM@SiO2) and the fluorinated nano-silica (F-SiO2) were simultaneously introduced into polyvinylidene fluoride (PVDF) to construct a micro-/nano-/nano-hierarchical structure on the PVDF/F-HGM@SiO2/F-SiO2 surface. Hence, a durable air layer was formed due to the suitable rough structure in conjunction with low-surface-energy groups, which endows the coating with outstanding crude-oil-repellency. Moreover, based on the self-designed test device, the coating showed an excellent anti-waxing deposition ratio (R = 82.76 %). Significantly, on the basis of the morphologies, wettability, and anti-waxing performance of the coatings, the main liquid-wettability, and anti-waxing mechanisms were illustrated, which revealed the inseparable relationship between them. The durability of the coating was investigated through mechanical/chemical damage tests (the OCA and OSA were kept above 140° and below 30°, respectively). Therefore, this bioinspired superamphiphobic coating is expected to open up new avenues for the design and fabrication of anti-waxing coating, which present enormous application value in oily/corrosive environments.