N-type small molecule electron transport materials with D-A-D conjugated core for non-fullerene organic solar cells

Two novel D-A-D-type small molecular conjugated electrolytes (DPPN2TPA and DPPM2TPA) with strong self-doping effects were designed and synthesized. The DPPM2TPA features excellent universality and can maintain 90% PCE when the thickness is up to 37 nm, a PCE of 17.31% was achieved in the NOSCs of PM...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2023-01, Vol.452, p.139260, Article 139260
Hauptverfasser: Zhou, Dan, Li, Yubing, Zhang, Hehui, Zheng, Haolan, Shen, Xingxing, You, Wen, Hu, Lin, Han, Liangjing, Tong, Yongfen, Chen, Lie
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Two novel D-A-D-type small molecular conjugated electrolytes (DPPN2TPA and DPPM2TPA) with strong self-doping effects were designed and synthesized. The DPPM2TPA features excellent universality and can maintain 90% PCE when the thickness is up to 37 nm, a PCE of 17.31% was achieved in the NOSCs of PM6: BTP-eC9. [Display omitted] •Two D-A-D-type ETMs with DPP as the acceptor, TPA as the donor have been synthesized.•The electron-deficient DPP is double-doped by the amine and the electron-rich TPA.•Due to extra interfacial dipoles from imidazolium, DPPM2TPA exhibits preferable PCE.•The PM6: BTP-eC9-based NOSCs with DPPM2TPA as ETM deliver an excellent PCE of 17.31%. Two D (donor)-A (acceptor)-D-type small-molecular conjugated electrolytes (SMCEs) electron transport materials (ETMs) with self-doping effects, namely DPPN2TPA and DPPM2TPA, were successfully synthesized by introducing diketopyrrolopyrrole (DPP) as the electron acceptor, triphenylamine (TPA) as the electron donor and quaternary ammonium or imidazolium salts as polar pendants. Impressively, the electron-deficient group DPP is double-doped by the amine-based groups and the electron-rich groups TPA, thus DPPN2TPA and DPPM2TPA exhibit prominent intramolecular charge transfer (ICT) and distinct n-type self-doping property. These characters can increase the electron mobility and ameliorate the work function (WF) of the stable metal Ag to create ohmic contact, making for significant elevated photovoltaic performance of the SMCEs. Especially, DPPM2TPA emerges more prominent optoelectronic property than DPPN2TPA due to the extra interfacial dipoles generated by the tertiary amine of imidazole moieties. The PM6:Y6-based non-fullerene organic solar cells (NOSCs) with DPPN2TPA and DPPM2TPA as ETMs achieve excellent power conversion efficiency (PCE) of 15.93 % and 16.40 %, respectively. It is noticeably superior to the NOSC with classical ETM PDINO (15.35 %). Delightfully, the PCE remained at 14.64 % (≈90 %) when the thickness of DPPM2TPA film reached 37 nm, which manifests that DPPM2TPA has satisfactory thickness insensitivity and can be used to manufacture large-scale devices. Furthermore, DPPM2TPA has conspicuous universality, when DPPM2TPA ETM was applied to the device with PM6: BTP-eC9, a remarkable PCE of 17.31 % was realized. These results demonstrate the potential of DPPM2TPA for industrialized large-scale manufacturing and afford an effective approach for exploring high-performance D-A-D SMCEs NOSCs.
ISSN:1385-8947
1873-3212
DOI:10.1016/j.cej.2022.139260