Slippery coating without loss of lubricant
•Fabrication of slippery coating without loss of lubricant.•The resistance to the loss of lubricants.•Quantum chemical calculation of interaction energy between silicone oil and polyorganosilazane molecules.•The better anti-icing and anti-corrosion ability. Inspired by Nepenthes pitcher plant, slipp...
Gespeichert in:
Veröffentlicht in: | Chemical engineering journal (Lausanne, Switzerland : 1996) Switzerland : 1996), 2022-09, Vol.444, p.136606, Article 136606 |
---|---|
Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | •Fabrication of slippery coating without loss of lubricant.•The resistance to the loss of lubricants.•Quantum chemical calculation of interaction energy between silicone oil and polyorganosilazane molecules.•The better anti-icing and anti-corrosion ability.
Inspired by Nepenthes pitcher plant, slippery liquid-infused porous surface (SLIPS) has been received great concern. However, the fabrication and application of SLIPS generally cannot avoid the complicated construction of the micro/nanostructures and the loss of the lubricant. In addition, despite another slippery covalently surface can exhibit liquid-like properties of SLIPS, the chemical grafting reaction conditions are usually harsh and low-efficiency. To address these challenges, herein an easy, high-efficiency and non-fluorinated strategy to create a flat slippery coating without the loss of lubricant (SCLL) was reported. The better flatness and the own hydrophobicity of the cured polyorganosilazane (PSZ) combined with the silicone oil molecules on its surface endowed the SCLL excellent slippery property. Moreover, the strong intermolecular attraction and the large adhesion work originated from the chemical affinity between PSZ and silicone oil molecules allowed the proposed SCLL with no lubricant loss. We further showed the SCLL has promising application prospects in the ice resistance, indicated by its longer icing-delaying time and lower ice adhesion strength, compared with original Al surface. Our envision is that SCLL may be applied in the practical industry production. |
---|---|
ISSN: | 1385-8947 1873-3212 |
DOI: | 10.1016/j.cej.2022.136606 |