Composites of NiSe2@C hollow nanospheres wrapped with Ti3C2Tx MXene for synergistic enhanced sodium storage

[Display omitted] •A 3D NiSe2@C@MXene composites was engineered for SIBs anodes.•MXene provide dual structural confinement on carbon coated NiSe2 hollow nanospheres.•The composites were endowed with enhanced electrochemical activity, rapid electrochemical dynamic.•The NiSe2@C@MXene composites exhibit excellent sodium storage performance. Sodium-ion batteries (SIBs) have the virtues of abundant sodium source and low price, but the serious volume expansion and poor cycle stability caused by the large sodium ion radius limit its practical application. Herein, we develop a three-dimensional (3D) Ti3C2Tx MXene wrapped NiSe2@C hollow nanospheres (NiSe2@C@MXene) composites for advanced sodium ion storage. The electrostatic self-assembly of MXene on NiSe2@C hollow nanospheres not only provides dual structural confinement on carbon coated NiSe2, but also efficiently inhibits the self-stacking of MXene. Taking advantage of the highly conductive 3D hierarchical network, the NiSe2@C@MXene electrode is endowed with enhanced electrochemical activity, fast electrochemical dynamic and abundant spatially confined active sites, leading to high reversibility and stable structural integration. Consequently, the NiSe2@C@MXene electrode provides a synergistic enhanced capacity of 327 mA h g−1 at 2000 mA g−1 after 4000 cycles, indicating high-rate capability and long-term stability. This work provides a new route toward developing MXene engineered Ni-based electrode materials for high-performance sodium storage.