Supramolecular architecture, hydrogen bonding assembly and Hirshfeld surface analysis of charge transfer adipate salt of 4-methoxyaniline

A novel hydrogen bonded bis(4-methoxyanilinium) adipate (4MAA) singlecrystal has been successfully grown and the corresponding crystal structure has been reported first time. SCXRD analysis reveals that 4MAA crystallizes in triclinic unit cell with P1¯ space group. The crystal structures of the 4MAA was steadied by N–H···O and O–H···O three dimensional hydrogen bonding networks. The centrosymmetrically related two intermolecular NH…O hydrogen bonds are connecting the ions through R22(8) and R44(12) ring motifs as primary motifs. Furthermore, Hirshfeld surface and 2D Fingerprint plot were generated and explained. [Display omitted]