Developments of the heterogeneous and homogeneous CO2 hydrogenation to value-added C2+-based hydrocarbons and oxygenated products

This review records the recent developments on CO2 hydrogenation reactions for the formation of value-added products such as C2H4, C2H5OH, C2H6, DME, higher hydrocarbons, alcohols, DMM and aromatic compounds. [Display omitted] •CO2 hydrogenation to C2+ products including gasoline as well as jet fuel are highly beneficial.•We have compiled and analyzed the important features from both experimental and theoretical perspectives.•The reason behind high catalytic activity of various bifunctional catalysts have been reviewed and recapped.•The possible schemes, current challenges, and the expected future research pathways has been presented. The escalating energy demand has persuaded the scientific community to advent efficient methods for the utilization of carbon neutral fuels with existing technologies. CO2, being a major component of greenhouse gases, draws more attention towards carbon capture and utilization (CCU) into energy rich products. Among all the CCU products, higher hydrocarbons, alcohols, and ethers are more desirable than low carbon-based products due to their featuring high energy density and minimal emissions. In this context, major advancements are being achieved in the production of fuels and fuel additives like ethanol, ethylene, ethane, dimethyl ether, light olefins (C2–C4 olefins), jet fuels (C8–C16 alkanes and cycloalkanes), aromatic products, etc. from CO2 hydrogenation reaction. Hence, it is imperative to compile and analyze its important features regarding catalyst environment, mechanistic insights, conversion efficiency, product selectivity and so on from both experimental and theoretical perspectives. In our review, we comprehensively evaluate the developments towards promoting CO2 hydrogenation to high carbon-based products. We intend to present the possible schemes, current challenges, and the expected future research pathways towards designing efficient catalytic systems for CO2 reduction reaction. We expect such a review is of immense research interest and will motivate the scientific world in the direction of large-scale industrial production of clean energy fuels.