A manual operated and eco-friendly plasma-assisted polymerization method for enhancing surface weather resistance of insulation

[Display omitted] •Novel dry processing method for contaminated insulation recovery and service life prolonging.•Plasma-assisted polymerization based on activation and re-assembly of alkoxysilane.•Better weather resistance and electrical performances of on-site insulations after plasma treatment.•More effective, eco-friendly and controllable compared to common processing methods. With the increasing demand for high-voltage long-distance power transmission, insulation as the first protection of power system, faces serious challenges from material degradation caused by moisture invading, surface contamination and pollution flashover. Addressing the issue requires significant effort and may cause harmful by-product emission from large-scale wet type material processing. In this work, a novel eco-friendly dry treatment method based on manual operated Air/Alkoxysilane(PMDMS)/plasma is developed to enhance weather resistance and electrical performances of contaminated insulation. Tiny amounts of harmless reaction medium are transmitted to plasma through controllable air bubbling, and it implements precise dry type processing on material surface. Plasma pulverizes pre-existing contamination and synchronously activates hydrolysis-polymerization of PMDMS to deposit Si-containing protection layer (Si-O2, Si-CH3) on surface. It is demonstrated that the plasma treatment inhibits dirt pollution and electrical erosion of on-site 110 kV silicone rubber (SIR), and the electrical and hydrophobicity properties are both promoted. Flashover voltage increases from 4.65 to 8.71 kV, and water contact angle increases from 138.27° to 146.41°. Overall, this newly-developed dry portable plasma treatment strategy for insulation enhancement avoids environment pollution and economic losses, and provides a scalable avenue for on-site insulation recovery and service life prolonging.