Electron-stimulated desorption kinetics of ultra-thin LiCl films on graphene

[Display omitted] •Electron-Stimulated desorption of ultra-thin LiCl films on graphene.•Evolution of desorption kinetics through two desorption regimes.•Differences between Photon- and Electron-Stimulated desorption kinetics. Ultra-thin alkali halide films are an important substrate for studying single quantum objects at the atomic scale, as they serve as decoupling scaffolds. However, their stability upon exposure to electrons and photons, the most common probes used to study nanomaterials, is not fully understood. Here we present a study of the evolution of the structure of ultra-thin LiCl films, grown on graphene, upon low-energy electron irradiation by means of microspot-low-energy electron diffraction and microscopy. We find that the intensity of the LiCl diffraction spots irradiated at various electron energies follows a bi-exponential decay function, which can be rationalized by two different desorption regimes. In addition, we detect a change in the work function caused by the electron irradiation, confirming desorption of the LiCl film from the graphene layer. We understand the underlying mechanisms for the electron-induced desorption of the salt film in terms of the evolution of the elementary quasiparticles involved in the process: holes, excitons and F and H center pairs. Moreover, a direct comparison of the electron-induced and the soft X-ray photon-induced processes reveal that, in addition to LiCl desorption, the intercalation of lithium into graphene reported for X-ray induced desorption does not take place in electron-stimulated desorption.