Highly effective antibacterial properties of self-formed Ag nanoparticles/Zr-Ag granular films

[Display omitted] •A convenient method prepared Ag NPs/Zr-Ag films with high-effective antibacterial properties.•Synergistic effect of Ag NPs and Ag+ enhances the antibacterial properties of Zr-Ag films.•A great number of “clean” monodisperse Ag NPs are self-assembled on different substrates.•Zr add...

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Veröffentlicht in:Applied surface science 2023-06, Vol.622, p.156929, Article 156929
Hauptverfasser: Shi, Pengyan, Sun, Haoliang, Zhang, Haoge, Li, Saibo, Liang, Shihao, Lv, Yuanjiang, Wang, Guangxin
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Sprache:eng
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Zusammenfassung:[Display omitted] •A convenient method prepared Ag NPs/Zr-Ag films with high-effective antibacterial properties.•Synergistic effect of Ag NPs and Ag+ enhances the antibacterial properties of Zr-Ag films.•A great number of “clean” monodisperse Ag NPs are self-assembled on different substrates.•Zr addition promotes the self-assembly of Ag NPs on the film surface. Zr-Ag granular films are prepared by magnetron sputtering, on which monodisperse Ag nanoparticles are controllably fabricated through thermal annealing the thin films. The self-formation behaviors of Ag nanoparticles are temperature and Ag content dependent. At the annealing temperature of 360 ℃, the Zr-41.0 wt% Ag granular films have the highest number density of Ag nanoparticles. In vitro antibacterial experiments show that the Ag nanoparticles/Zr-Ag granular films exhibit an excellent antibacterial property, even more than 99.99% for both Escherichia coli and Staphylococcus aureus. The remarkable antibacterial activity can be ascribed to the release of Ag+ from Ag nanoparticles/Zr-Ag granular films and mechanical antibacterial effect of Ag nanoparticles. The results are helpful to the flexible fabrication and development of granular films with high antibacterial performances on different substrates.
ISSN:0169-4332
1873-5584
DOI:10.1016/j.apsusc.2023.156929