Exploring the Behavior of Quartz-Glauconite-Phosphate Flotation System

Glauconite is a clay mineral that is most probably mined with phosphate and represents a challenge for phosphate upgrading by flotation. Reverse flotation is a common method for removing silica and silicate from siliceous phosphate. Thus, a systemic study was conducted to determine the effect of clay and its interactions with siliceous phosphate ore components on its cleaning by flotation. The flotation of each mineral (phosphate, quartz, and clay) was tested in terms of product recovery using quaternary amine at pH 9. In addition, the settling behavior of each mineral was investigated with and without quaternary amine. Binary and tertiary systems were studied to investigate the interactions between the main ore-containing minerals. The results of each mineral flotation test showed that quartz has the highest floatability, with low floatability of both phosphate and glauconite by quaternary amine. The presence of glauconite does not affect the phosphate recovery, whereas glauconite reduces the quartz floatability, which deteriorates the quartz removal from phosphate. Finally, the interaction mechanisms in the different systems are illustrated.