Highly sensitive determination of nitrite using a carbon ionic liquid electrode modified with Fe3O4 magnetic nanoparticle

A carbon ionic liquid electrode modified with Fe 3 O 4 magnetic nanoparticle (Fe 3 O 4 NPs/CILE) was employed for nitrite determination by cyclic voltammetry. The results showed that the Fe 3 O 4 NPs/CILE exhibited a significant improvement in the oxidation peak current of nitrite. After optimizing...

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Veröffentlicht in:Journal of the Iranian Chemical Society 2015-07, Vol.12 (7), p.1293-1301
Hauptverfasser: Absalan, Ghodratollah, Akhond, Morteza, Bananejad, Asma, Ershadifar, Hamid
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Sprache:eng
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Zusammenfassung:A carbon ionic liquid electrode modified with Fe 3 O 4 magnetic nanoparticle (Fe 3 O 4 NPs/CILE) was employed for nitrite determination by cyclic voltammetry. The results showed that the Fe 3 O 4 NPs/CILE exhibited a significant improvement in the oxidation peak current of nitrite. After optimizing the operational conditions, a linear response range from 10 to 900 µmol L −1 with a low detection limit of 0.70 µmol L −1 was obtained. The proposed sensor was stable with a sensitivity of 0.0402 μA μmol −1  L and good repeatability evaluated in terms of relative standard deviation (RSD 
ISSN:1735-207X
1735-2428
DOI:10.1007/s13738-015-0594-z