Vibrational spectra of H2O and CF4 molecules using Lie algebraic approach

In this paper, we introduce one dimensional vibron model to analyze the fundamental, overtone and combination modes of CF 4 molecule and both stretching, bending vibrational mode of bent H 2 O molecule up to first overtone with few algebraic parameters. Using the model Hamiltonian, we reported here...

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Veröffentlicht in:Indian journal of physics 2010-06, Vol.84 (6), p.659-664
Hauptverfasser: Choudhury, Joydeep, Karumuri, Srinivasa Rao, Sinha, Rupali, Sarkar, Nirmal Kumar, Bhattacharjee, Ramendu
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Sprache:eng
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Zusammenfassung:In this paper, we introduce one dimensional vibron model to analyze the fundamental, overtone and combination modes of CF 4 molecule and both stretching, bending vibrational mode of bent H 2 O molecule up to first overtone with few algebraic parameters. Using the model Hamiltonian, we reported here better results for the vibrational spectra of H 2 O. Our analysis suggests some reassignments of levels and predicts location of states in case of CF 4 molecule which was not yet observed.
ISSN:0019-5480
0974-9845
DOI:10.1007/s12648-010-0067-2