Optical characterization of CdSe/Dy3+-doped silica matrices

Cadmium selenide nanocrystals along with dysprosium ions are doped in silica matrices through sol-gel route. The optical bandgap and size of the CdSe nanocrystals are calculated from the absorption spectrum. The size of the CdSe nanocrystallites is also evaluated from the TEM measurements. The fluor...

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Veröffentlicht in:Pramāṇa 2010-11, Vol.75 (5), p.999-1004
Hauptverfasser: Jyothy, P. V., Rejikumar, P. R., Vinoy, Thomas, Kartika, S., Unnikrishnan, N. V.
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Sprache:eng
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Zusammenfassung:Cadmium selenide nanocrystals along with dysprosium ions are doped in silica matrices through sol-gel route. The optical bandgap and size of the CdSe nanocrystals are calculated from the absorption spectrum. The size of the CdSe nanocrystallites is also evaluated from the TEM measurements. The fluorescence intensities are compared for SiO 2 -Dy 3+ and CdSe-doped SiO 2 -Dy 3+ . The fluorescence intensity of Dy 3+ is considerably increased in the presence of CdSe nanocrystals.
ISSN:0304-4289
0973-7111
DOI:10.1007/s12043-010-0187-4