Foam carbon loading Fe3O4 nanoparticles for superior lithium-ion batteries anode material
A novel foam carbon (FC) material with partly graphitized and 3D interlaced thin carbon interlayer as skeleton was synthesized by an eco-friendly route. Fe 3 O 4 nanoparticles (~20 nm) were loaded homogenously into pores of FC through simple impregnating and thermal treatment. The electrochemical pr...
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Veröffentlicht in: | Ionics 2015-07, Vol.21 (7), p.1901-1908 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A novel foam carbon (FC) material with partly graphitized and 3D interlaced thin carbon interlayer as skeleton was synthesized by an eco-friendly route. Fe
3
O
4
nanoparticles (~20 nm) were loaded homogenously into pores of FC through simple impregnating and thermal treatment. The electrochemical property of Fe
3
O
4
/FC composite was evaluated by galvanostatic discharge/charge cycling, cyclic voltammetry, and impedance spectroscopy. The results showed that Fe
3
O
4
/FC nanocomposite possessed superior cycling stability and C-rate performance. A stable capacity of 1100 mAh g
−1
was maintained at a current density of 0.1 C and the reversible capacity reached to 440 mAh g
−1
at 5 C in C-rate test. The excellent performance is attributed to the desired composite structure of Fe
3
O
4
/FC, including homogenous distribution of nano-sized Fe
3
O
4
particles, 3D interconnected electron transmission carbon network, and abundant interlinked pore channel, which guarantee quick electron and Li
+
transfer as well as electrode structure undamaged during (de)lithiation process. |
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ISSN: | 0947-7047 1862-0760 |
DOI: | 10.1007/s11581-015-1369-3 |