Towards a Practical and Efficient Copper-Catalyzed Trifluoromethylation of Aryl Halides

The first copper-catalyzed trifluoromethylation of aryl halides was developed that utilizes inexpensive trifluoroacetates. Providing low concentrations of the most economically attractive and atom-efficient trifluoromethylation reagent this new protocol is advantageous compared to known procedures b...

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Veröffentlicht in:	Topics in catalysis 2012-07, Vol.55 (7-10), p.426-431
Hauptverfasser:	Schareina, Thomas, Wu, Xiao-Feng, Zapf, Alexander, Cotté, Alain, Gotta, Matthias, Beller, Matthias
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Industrial Chemistry/Chemical Engineering Original Paper Pharmacy Physical Chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The first copper-catalyzed trifluoromethylation of aryl halides was developed that utilizes inexpensive trifluoroacetates. Providing low concentrations of the most economically attractive and atom-efficient trifluoromethylation reagent this new protocol is advantageous compared to known procedures both economically and ecologically.
ISSN:	1022-5528 1572-9028
DOI:	10.1007/s11244-012-9824-0