Specific features of the chemical behavior of sodium 3,4,5-tris(2-thienyl)-1,2-diphosphacyclopentadienide

Specific features of the chemical behavior of sodium 3,4,5-tris(2-thienyl)-1,2-diphosphacyclopentadienide

A new representative of 1,2-diphosphacyclopentadienide anions containing 2-thienyl substituents at carbon atoms was synthesized by the reaction of sodium polyphosphides with cyclopropenylphosphonium salts. The specific features of the chemical behavior of this compound were revealed by studying the...

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Veröffentlicht in:Russian chemical bulletin 2015-08, Vol.64 (8), p.1912-1918
Hauptverfasser: Kochetkova, L. R., Bezkishko, I. A., Miluykov, V. A., Islamov, D. R., Krivolapov, D. B., Kataeva, O. N., Sinyashin, O. G.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
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Zusammenfassung:A new representative of 1,2-diphosphacyclopentadienide anions containing 2-thienyl substituents at carbon atoms was synthesized by the reaction of sodium polyphosphides with cyclopropenylphosphonium salts. The specific features of the chemical behavior of this compound were revealed by studying the reactions with organic and heteroorganic electrophiles and with pentacarbonylmanganese bromide.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-015-1093-1