Synthesis of 3-aminomethyl-4-hydroxycoumarins and their retro-Mannich reaction in dimethyl sulfoxide

Hydrogenation of 3-formyl-4-hydroxycoumarin aliphatic imines leads to 3-aminomethyl-4-hydroxycoumarins, which undergo a retro-Mannich reaction in dimethyl sulfoxide containing even traces of water.

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Bibliographische Detailangaben
Veröffentlicht in:	Russian chemical bulletin 2015-02, Vol.64 (2), p.423-428
Hauptverfasser:	Milevskii, B. G., Chibisova, T. A., Solov´eva, N. P., Sukhorukov, A. Yu, Traven, V. F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Full Articles Inorganic Chemistry Organic Chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Hydrogenation of 3-formyl-4-hydroxycoumarin aliphatic imines leads to 3-aminomethyl-4-hydroxycoumarins, which undergo a retro-Mannich reaction in dimethyl sulfoxide containing even traces of water.
ISSN:	1066-5285 1573-9171
DOI:	10.1007/s11172-015-0879-5