Synthesis of new phosphorylated fullerene C60 derivatives soluble in polar solvents

Synthesis of new phosphorylated fullerene C60 derivatives soluble in polar solvents

A directed synthesis of new phosphorylated methanofullerenes containing acetonide fragments was accomplished for the first time, their chemical structure was confirmed by a combination of spectroscopic methods. Removal of the acetonide protection produced new phosphorrylated diol methanofullerenes,...

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Veröffentlicht in:Russian chemical bulletin 2014, Vol.63 (6), p.1386-1389
Hauptverfasser: Gubskaya, V. P., Fazleeva, G. M., Gil’mutdinova, A. A., Latypov, Sh. K., Sharafutdinova, D. R., Nuretdinov, I. A., Sinyashin, O. G.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
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Zusammenfassung:A directed synthesis of new phosphorylated methanofullerenes containing acetonide fragments was accomplished for the first time, their chemical structure was confirmed by a combination of spectroscopic methods. Removal of the acetonide protection produced new phosphorrylated diol methanofullerenes, their structure and properties were studied. The diol methanofullerenes are well soluble in polar solvents, including a mixture of DMSO-water (1: 9).
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-014-0607-6