Model for thermal self-ignition of two-phase system in a batch reactor

A mathematical model for thermal self-ignition of a two-phase system with a homogeneous bimolecular exothermic reaction in a batch reactor is proposed. The influence of the volumetric ratio of phases and the specific surface area of exchange interface on the parameters of thermal ignition of the sys...

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Veröffentlicht in:	Russian chemical bulletin 2012-06, Vol.61 (6), p.1049-1056
Hauptverfasser:	Deyun, E. V., Kustova, L. V., Kazakov, A. I.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Full Articles Inorganic Chemistry Organic Chemistry
Online-Zugang:	Volltext
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Zusammenfassung:	A mathematical model for thermal self-ignition of a two-phase system with a homogeneous bimolecular exothermic reaction in a batch reactor is proposed. The influence of the volumetric ratio of phases and the specific surface area of exchange interface on the parameters of thermal ignition of the system was studied. The kinetic dependences of reactant concentrations and the reactor heating dynamics were investigated.
ISSN:	1066-5285 1573-9171
DOI:	10.1007/s11172-012-0142-2