The use of carboranylphosphite ligands in Rh-catalyzed hydroformylation of alkenes in supercritical carbon dioxide

Novel carborane-containing phosphites were synthesized. The efficiency of the ligands was tested in the Rh-catalyzed hydroformylation of styrene, hept-1-ene, and oct-1-ene in super-critical carbon dioxide (scCO 2 ) and toluene. The use of scCO 2 as the reaction medium allows one to attain higher con...

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Veröffentlicht in:	Russian chemical bulletin 2011-10, Vol.60 (10), p.2074-2077
Hauptverfasser:	Lyubimov, S. E., Petrovskii, P. V., Rastorguev, E. A., Verbitskaya, T. A., Kalinin, V. N., Davankov, V. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Full Articles Inorganic Chemistry Organic Chemistry
Online-Zugang:	Volltext
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Zusammenfassung:	Novel carborane-containing phosphites were synthesized. The efficiency of the ligands was tested in the Rh-catalyzed hydroformylation of styrene, hept-1-ene, and oct-1-ene in super-critical carbon dioxide (scCO 2 ) and toluene. The use of scCO 2 as the reaction medium allows one to attain higher conversions and regioselectivities compared to toluene.
ISSN:	1066-5285 1573-9171
DOI:	10.1007/s11172-011-0316-3